STRUCTURAL AND MAGNETIC CHARACTERIZATION OF A NOVEL HEPTANUCLEAR HYDROXO-BRIDGED COPPER(II) CLUSTER OF THE CORNER-SHARING DICUBANE TYPE

被引：59

作者：

REAL, JA

DEMUNNO, G

CHIAPPETTA, R

JULVE, M

LLORET, F

JOURNAUX, Y

COLIN, JC

BLONDIN, G

机构：

[1] UNIV VALENCIA, FAC QUIM, DEPT QUIM INORGAN, E-46100 BURJASSOT, SPAIN

[2] UNIV CALABRIA, DIPARTIMENTO CHIM, I-87030 Arcavacata Di Rende, ITALY

[3] UNIV PARIS 11, CHIM INORGAN LAB, CNRS, URA 420, F-91405 ORSAY, FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An energetically low‐lying octet ground state and ferromagnetic exchange interactions between seven CuII ions characterize the magnetic behavior of the complex cation in 1, whose novel Cu7(OH)8 framework is shown on the right, bpym = 2,2′‐bypyrimidine. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1184 / 1186

页数：3

共 17 条

[1] CRYSTAL AND MOLECULAR-STRUCTURES AND MAGNETIC-PROPERTIES OF TETRAMERIC COPPER(II) COMPLEXES WITH 3-HYDROXY-5-HYDROXYMETHYL-4-(4'-HYDROXY-4'-PHENYL-2'-AZABUT-1'-EN-1'-YL)-2-METHYLPYRIDINE (H2L3),([CU4L3]-L-4).9CH3OH AND 3-HYDROXY-5-HYDROXYMETHYL-4-(4'-HYDROXY-3'-METHYL-4'-PHENYL-2'AZABUT-1'-EN-1'-YL)-2-METHYLPYRIDINE (H2L1), ([CU4L1]-L-4).8CH3CH2OH - 2 COMPLEXES WITH FERROMAGNETIC GROUND-STATESO [J].