ADSORPTION OF N-ALKANE VAPORS ON WATER

被引：18

作者：

HAUXWELL, F

PALLAS, NR

PETHICA, BA

机构：

[1] COLUMBIA UNIV,HENRY KRUMB SCH MINES,LANGMUIR CTR COLLOIDS & INTERFACES,NEW YORK,NY 10027

[2] ICI COLOURS,MANCHESTER M9 3DA,ENGLAND

[3] BP RES,CLEVELAND,OH 44128

来源：

LANGMUIR | 1992年 / 8卷 / 02期

关键词：

D O I：

10.1021/la00038a049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The standard free energies, enthalpies, and entropies for the adsorption of the vapors of four normal alkanes (C5 to C8) at the surface of water are derived from experimental data on the surface pressure as a function of vapor pressure. The loss of entropy on adsorption is close to that expected from the loss of one of translational mode and all the chain configuration degrees of freedom.

引用

页码：602 / 603

页数：2