POTASSIUM TRIISOPROPYLSILANETHIOLATE - VINYL AND ARYL SULFIDES THROUGH PD-CATALYZED CROSS-COUPLING

被引：44

作者：

RANE, AM ^{[1
]}

MIRANDA, EI ^{[1
]}

SODERQUIST, JA ^{[1
]}

机构：

[1] UNIV PUERTO RICO,DEPT CHEM,RIO PIEDRAS,PR 00931

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)76870-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinyl and aryl halides are efficiently converted, under Pd catalysis, with KSTIPS (1) to the corresponding silyl sulfides (2, 3). The naphthyl derivative was easily hydrolyzed to the mercaptan 4, or alkylated or alkenylated to provide unsymmetrical sulfides (5, 6).

引用

页码：3225 / 3226

页数：2

共 10 条

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