共 3 条
- [1] LIVING POLYMERIZATION OF EPOXIDES WITH METALLOPORPHYRIN AND SYNTHESIS OF BLOCK COPOLYMERS WITH CONTROLLED CHAIN LENGTHS[J]. MACROMOLECULES, 1981, 14 (05) : 1162 - 1166AIDA, TINOUE, S
- [2] INOUE S, 1989, FRONTIERS MACROMOLEC, P73
PRECISE CONTROL OF POLYMER SYNTHESIS WITH A NEW CATALYST
被引：3
作者：
INOUE, S
机构：
[1] Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo, Tokyo 113, Hongo 7-3-1, Bunkyo-ku
来源：
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES
|
1991年
/
67卷
/
08期
关键词：
MACROMOLECULE;
POLYMERIZATION;
PORPHYRIN;
D O I：
10.2183/pjab.67.144
中图分类号：
O [数理科学和化学];
P [天文学、地球科学];
Q [生物科学];
N [自然科学总论];
学科分类号：
07 ;
0710 ;
09 ;
摘要：
Aluminum porphyrin is an excellent catalyst for the synthesis of polymers from a wide variety of monomers such as epoxide, lactone, and methacrylic ester, to give the polymers with controlled molecular weight. A novel catalyst system composed of aluminum porphyrin and an organoaluminum compound with bulky substituents brings about a remarkably accelerated reaction retaining the controlled molecular weight of the polymer.
引用
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页码：144 / 147
页数：4
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