SYNTHESIS OF CIS-DECALIN DERIVATIVE VIA PI-ALLYLPALLADIUM INTERMEDIATE AND ITS TRANSFORMATION TO USEFULLY FUNCTIONALIZED TRANS-DECALIN DERIVATIVE

被引：9

作者：

TAKEMOTO, T

NISHIKIMI, Y

SODEOKA, M

SHIBASAKI, M

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

[2] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)92680-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 15 or 16 with Pd(PPh3)4 (10 mol %) and NaH (1.2 equiv) afforded the cis-decalin derivative 18 stereoselectively in high yield, which was effectively transformed into the usefully functionalized trans-decalin derivative 29.

引用

页码：3527 / 3530

页数：4

共 15 条

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