RUTHENIUM-CATALYZED DISPROPORTIONATION BETWEEN VINYLSILANES AND MONO-SUBSTITUTED ALKENES VIA SILYL GROUP TRANSFER

被引：145

作者：

WAKATSUKI, Y ^{[1
]}

YAMAZAKI, H ^{[1
]}

NAKANO, M ^{[1
]}

YAMAMOTO, Y ^{[1
]}

机构：

[1] TOHO UNIV,FAC SCI,FUNABASHI,CHIBA 274,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000703

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective cross-disproportion between vinylsilanes and various mono-substituted alkenes is catalysed by [RuCl(CO)H(PPh3)3] 1; the mechanism of this reaction has been elucidated based on reactions of 1 with vinylsilanes as well as those of the resulting ruthenium-silyl complex with alkenes.

引用

页码：703 / 704

页数：2

共 9 条

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