DETERMINATION OF THE KINETICS OF VINYL RADICAL REACTIONS BY THE CHARACTERISTIC VISIBLE ABSORPTION-SPECTRA OF VINYLPEROXYL RADICALS

被引：45

作者：

MERTENS, R ^{[1
]}

VONSONNTAG, C ^{[1
]}

机构：

[1] MAX PLANCK INST STRAHLENCHEM,D-45413 MULHEIM,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1002/anie.199412621

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vinylperoxyl radicals surprisingly absorb in the visible region, whereas other peroxyl radicals absorb in the UV. Thus the kinetics of reactions of both vinylperoxyl radicals and vinyl radicals can be studied conveniently. The peroxyl radicals are formed by pulse radiolysis of oxygen‐containing aqueous solutions of vinyl halides like 1 [Eq. (a)]. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1262 / 1264

页数：3

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