[(NI(3,2,3-TET)(MU-NCO))N](CLO4)N - STRUCTURAL CHARACTERIZATION OF THE 1ST MONODIMENSIONAL NICKEL(II)-CYANATO SYSTEM WITH A DESCRIPTION OF ITS FERROMAGNETIC COUPLING

被引：21

作者：

ESCUER, A ^{[1
]}

VICENTE, R ^{[1
]}

RIBAS, J ^{[1
]}

ELFALLAH, MS ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT CRISTALLOG & MINERAL,E-08028 BARCELONA,SPAIN

来源：

INORGANICA CHIMICA ACTA | 1994年 / 216卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; NICKEL COMPLEXES; CYANATE COMPLEXES; MAGNETISM;

D O I：

10.1016/0020-1693(93)03727-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been characterized by means of X-ray crystallography. The cyanato ligand acts as a bridge between the square planar [Ni(3,2,3-tet)]2+ entities (3,2,3-tet = N,N'-bis(3-aminopropyl)-1,2-ethanediamine), giving an unprecedented chain structure. Crystal data for [{Ni(3,2,3-tet)(mu-NCO)}n](ClO4)n: FW = 374.47, monoclinic, space group P2(1)/n, a = 10.587(2), b = 12.395(2), c = 11.871(2) angstrom, beta = 92.00(1)-degrees, Z = 4, D(c) = 1.597 g cm-3, R = 0.038, R(w) = 0.041. The magnetic susceptibility data indicate weak ferromagnetic coupling.

引用

页码：5 / 7

页数：3

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