AN MNDO STUDY OF SUBSTITUENT EFFECTS IN CARBOCATIONS - THE UNIMPORTANCE OF INDUCTIVE EFFECTS

被引：15

作者：

AISSANI, AM

BAUM, JC

LANGLER, RF

GINSBURG, JL

机构：

[1] FLORIDA INST TECHNOL,DEPT CHEM,MELBOURNE,FL 32901

[2] ST MARYS UNIV,DEPT CHEM,HALIFAX B3H 3C3,NS,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 03期

关键词：

D O I：

10.1139/v86-085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：532 / 538

页数：7

共 31 条

[1] TWISTING IN ALKENE ION RADICALS [J].

BELLVILLE, DJ ;

BAULD, NL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (01) :294-295

[2] THE ELONGATED (ONE ELECTRON) CARBON CARBON BOND IN SIGMA-ORGANIC AND N-ORGANIC CATION RADICALS [J].

BELLVILLE, DJ ;

BAULD, NL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5700-5702

[3] GROUND-STATES OF MOLECULES .25. MINDO-3 - IMPROVED VERSION OF MINDO SEMIEMPIRICAL SCF-MO METHOD [J].

BINGHAM, RC ;

DEWAR, MJS ;

LO, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1285-1293

[4] THE REGIOSPECIFIC ALKYLATION OF AMIDES - MNDO SCF-MO CALCULATIONS [J].

CHALLIS, BC ;

ILEY, JN ;

RZEPA, HS .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (07) :1037-1041

[5] STABILIZATION OF ALPHA-KETO CATIONS BY CARBONYL CONJUGATION [J].

CREARY, X .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) :2463-2465

[6] ION-PAIRS OF BENZYLIC CATIONS, A THEORETICAL-STUDY [J].

DECORET, C ;

ROYER, J ;

DANNENBERG, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (20) :4074-4076

[7]

DEWAR MJS, 1977, J AM CHEM SOC, V99, P4889

[8] MNDO CALCULATIONS OF PROTON AND METHYL-CATION AND ETHYL-CATION AFFINITIES OF NEUTRAL CARBON, NITROGEN, AND OXYGEN BASES [J].

FORD, GP ;

SCRIBNER, JD .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 1983, 4 (04) :594-604

[9] MNDO CALCULATIONS ON THE UNIMOLECULAR CO LOSS FROM ISOMERIC C3H5CO+ IONS [J].

FRENKING, G ;

SCHMIDT, J ;

SCHWARZ, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1980, 35 (08) :1031-1034

[10] H-ALPHA-CN VERSUS H-BETA-CN RATE RATIOS IN THE SOLVOLYSIS OF SULFONATE ESTERS IN UNCONSTRAINED SYSTEMS - ADDITIONAL EVIDENCE FOR CONJUGATIVE STABILIZATION OF ATTACHED CARBOCATIONS BY THE CYANO MOIETY [J].

GASSMAN, PG ;

SAITO, K .

TETRAHEDRON LETTERS, 1981, 22 (14) :1311-1314

← 1 2 3 4 →