POLY(PHENYLENEVINYLENE) BEARING BUILT-IN TERT-BUTYLNITROXIDE - A POLYRADICAL FERROMAGNETICALLY COUPLED IN THE INTRACHAIN

被引：41

作者：

KANEKO, T ^{[1
]}

TORIU, S ^{[1
]}

KUZUMAKI, Y ^{[1
]}

NISHIDE, H ^{[1
]}

TSUCHIDA, E ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT POLYMER CHEM, TOKYO 169, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(1,4- or 1,2-phenylenevinylene)s bearing a 2- or 4-substituted nitroxide radical were synthesized by polymerizing [bromo[N-tert-butyl-N-(trialkylsiloxy)amino]]-styrenes with a palladium catalyst. The polyradicals were chemically stable, and their ESR and SQUID measurements indicated an intramolecular and through-bond ferromagnetic coupling.

引用

页码：2135 / 2138

页数：4

共 24 条

[1] ANOMALOUS PARAMAGNETISM OF COPPER ACETATE
BLEANEY, B
BOWERS, KD
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119): : 451 - 465
[2] SYNTHESES AND MAGNETIC-PROPERTIES OF POLY(PHENYLACETYLENES) CARRYING A (1-OXIDO-3-OXY-4,4,5,5-TETRAMETHYL-2-IMIDAZOLIN-2-YL) GROUP AT THE META OR PARA POSITION OF THE PHENYL RING
FUJII, A
ISHIDA, T
KOGA, N
IWAMURA, H
[J]. MACROMOLECULES, 1991, 24 (05) : 1077 - 1082
[3] CONDUCTIVITY ANISOTROPY IN ORIENTED POLY(P-PHENYLENE VINYLENE)
GAGNON, DR
CAPISTRAN, JD
KARASZ, FE
LENZ, RW
[J]. POLYMER BULLETIN, 1984, 12 (04) : 293 - 298
[4] GATTESCHI D, 1991, MAGNETIC MOL MATERIA
[5] HEITZ W, 1988, MAKROMOL CHEM, V189, P119
[6] IWAMURA H, 1993, MOL CRYST LIQ CRYST, V232
[7] HIGH-SPIN HYDROCARBONS
KLEIN, DJ
NELIN, CJ
ALEXANDER, S
MATSEN, FA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (06) : 3101 - 3108
[8] KOSSMEHL GA, 1989, HDB CONDUCTING POLYM, pCH10
[9] SEMIEMPIRICAL STUDY OF ELECTRON EXCHANGE INTERACTION IN ORGANIC HIGH-SPIN PI-SYSTEMS - CLASSIFYING STRUCTURAL EFFECTS IN ORGANIC MAGNETIC MOLECULES
LAHTI, PM
ICHIMURA, AS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (09) : 3030 - 3042
[10] MOLECULAR DESIGN, SYNTHESIS, AND MAGNETIC CHARACTERIZATION OF POLY (PHENYLACETYLENE) WITH PI-TOPOREGULATED PENDANT NITRONYL NITROXIDE RADICALS AS MODELS FOR ORGANIC SUPERPARAMAGNETS AND FERROMAGNETS
MIURA, Y
INUI, K
YAMAGUCHI, E
INOUE, M
TEKI, Y
TAKUI, T
ITOH, K
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1992, 30 (06) : 959 - 966

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