CATIONIC POLYMERIZATION OF VINYL AND CYCLIC ETHERS IN SUPERCRITICAL AND LIQUID CARBON-DIOXIDE

被引：61

作者：

CLARK, MR ^{[1
]}

DESIMONE, JM ^{[1
]}

机构：

[1] UNIV N CAROLINA, DEPT CHEM, VENABLE & KENAN LABS, CHAPEL HILL, NC 27599 USA

来源：

MACROMOLECULES | 1995年 / 28卷 / 08期

关键词：

Carbon dioxide - Ethers - Fourier transform infrared spectroscopy - Gel permeation chromatography - Initiators (chemical) - Liquefied gases - Molecular structure - Molecular weight distribution - Nuclear magnetic resonance spectroscopy - Paraffins - Synthesis (chemical);

D O I：

10.1021/ma00112a059

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Vinyl ethers and oxetanes was successfully polymerized cationically in carbon dioxide. These processes become heterogeneous using hydrocarbon vinyl ethers and oxytanes but high molar mass and high conversions can still be achieved. Homogeneous cationic polymerization are also possible with fluorocarbon-based alkyl vinyl ether and oxetane monomers. Polymerization occurs without incorporation of carbon dioxide into the polymer backbone for the systems used.

引用

页码：3002 / 3004

页数：3