PHYSICAL, SPECTRAL AND CHROMATOGRAPHIC PROPERTIES OF ALL 209 INDIVIDUAL PCB CONGENERS

被引：45

作者：

BOLGAR, M ^{[1
]}

CUNNINGHAM, J ^{[1
]}

COOPER, R ^{[1
]}

KOZLOSKI, R ^{[1
]}

HUBBALL, J ^{[1
]}

MILLER, DP ^{[1
]}

CRONE, T ^{[1
]}

KIMBALL, H ^{[1
]}

JANOOBY, A ^{[1
]}

MILLER, B ^{[1
]}

FAIRLESS, B ^{[1
]}

机构：

[1] US EPA,DIV ENVIRONM SERV,KANSAS CITY,KS 66115

来源：

CHEMOSPHERE | 1995年 / 31卷 / 02期

关键词：

D O I：

10.1016/0045-6535(95)00140-4

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Physical, spectral and chromatographic data for all 209 individual PCB congeners is presented. The individual congeners were synthesized and then isolated and purified. Recent emphasis on the source of the toxicity of commercial PCB formulations has increased the need for a complete set of the PCB congeners. Through the use of two capillary GC columns: 40% octadecyl/ 15% phenyl methyl siloxane and 50% phenyl methyl siloxane, it was possible to separate 201 PCB congeners with only four unresolved pairs. The data compiled in this study for all 209 congeners will aid in the identification of selected individual components of these environmental pollutants. The use of this data also presents the opportunity for the improved quantification of the commercial PCB formulations.

引用

页码：2687 / 2705

页数：19

共 35 条

[1] ANDERSON JW, 1992, PITTSBURGH C NEW ORL
[2] AYRES DC, 1971, B ENVIRON CONTAM TOX, V6, P209
[3] ISOMER-SPECIFIC IDENTIFICATION OF PCB CONGENERS IN TECHNICAL MIXTURES AND ENVIRONMENTAL-SAMPLES BY HRGC-ECD AND HRGC-MSD
BALLSCHMITER, K
SCHAFER, W
BUCHERT, H
[J]. FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1987, 326 (03): : 253 - 257
[4] BALLSCHMITTER F, 1988, Z ANAL CHEM, V332, P441
[5] ACCUMULATION OF AIRBORNE POLYCHLORINATED-BIPHENYLS IN FOLIAGE
BUCKLEY, EH
[J]. SCIENCE, 1982, 216 (4545) : 520 - 522
[6] A TWO-DIMENSIONAL REACTION GAS-CHROMATOGRAPHY SYSTEM FOR ISOMER-SPECIFIC DETERMINATION OF POLYCHLORINATED-BIPHENYLS
DUEBELBEIS, DO
KAPILA, S
CLEVENGER, T
YANDERS, AF
MANAHAN, SE
[J]. CHEMOSPHERE, 1989, 18 (1-6) : 101 - 108
[7] GLAUSCH A, 1994, HRC-J HIGH RES CHROM, V17, P347
[8] POLYCHLORINATED BIPHENYLS - SYNTHESIS OF SOME INDIVIDUAL CHLOROBIPHENYLS
HUTZINGER, O
SAFE, S
ZITKO, V
[J]. BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 1971, 6 (03) : 209 - +
[9] HUTZINGER O, 1974, CHEM PCBS CRC PRESS
[10] CHROMATOGRAPHIC TECHNIQUES IN ACCURATE ANALYSIS OF CHLOROBIPHENYLS
KANNAN, N
PETRICK, G
SCHULTZBULL, DE
DUINKER, JC
[J]. JOURNAL OF CHROMATOGRAPHY, 1993, 642 (1-2): : 425 - 434

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