PIG-LIVER ESTERASE-CATALYZED HYDROLYZES OF RACEMIC DIACETATES OF BICYCLIC COMPOUNDS AND INTERPRETATION OF THE ENANTIOMERIC SPECIFICITY OF PLE

被引：13

作者：

NAEMURA, K

TAKAHASHI, N

IDA, H

TANAKA, S

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pig liver esterase-catalyzed hydrolyses of racemic diacetates of bicyclic compounds, bicyclo[2.2.1]heptanes, bicyclo[2.2.2]octanes, and bicyclo[3.2.1]octanes gave the optically active monoacetates and diacetates. The enantiomeric specificity of PLE toward diacetates of racemic diol substrates was analyzed by using the active site model.

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页码：657 / 660

页数：4

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