CHEMISTRY OF MU-ETA(1)-ETA(2)ETA(ALPHA,BETA)-BUTADIYNYLS - CHAIN EXTENSION ON C-4 POLYCARBON LIGANDS

被引：18

作者：

BLENKIRON, P ^{[1
]}

PILETTE, D ^{[1
]}

CORRIGAN, JF ^{[1
]}

TAYLOR, NJ ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,DEPT CHEM,WATERLOO,ON N2L 3G1,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The binuclear butadiynyl compounds Ru-2(CO)(6)(mu-eta(1),eta(alpha,beta)(2)-C=C-C=CR)(mu-PPh(2)) (R = Bu(t) 1a or Ph 1b), with one pi-coordinated and one free triple bond, synthesised via thermolysis of Ru-3(CO)(11) (PPh(2)C=C-C=CR), react with NEt(2)H to generate the novel diethylaminobutatriene complexes Ru-2(CO)(6)[mu-eta(1),eta(1)-Et(2)N=C=C=C=C(H)R](mu-PPh(2)) (R = Bu(t) 2a or Ph 2b) in high yields: the molecular structures of la and 2a are determined.

引用

页码：2165 / 2166

页数：2

共 23 条

[1]

BARLUENGA J, 1995, ORGANOMETALLICS, V4, P1429

[2] NEW FAMILIES OF COORDINATED CARBON - OXIDATIVE COUPLING AND CROSS-COUPLING OF A TRANSITION-METAL BUTADIYNYL COMPLEX TO BIMETALLIC M-C-CC-CC-CC-C-M AND M-C-CC-CC-C-M ADDUCTS [J].

BRADY, M ;

WENG, WQ ;

GLADYSZ, JA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) :2655-2656

[3]

Brandsma L., 1988, PREPARATIVE ACETYLEN

[4] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[5] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .39. SYNTHESES OF NOVEL ALKYNYL-RUTHENIUM COMPLEXES - X-RAY STRUCTURES OF 2 FORMS OF (RU(PPH3)2(ETA-C5H5))2(MU-C4) AND OF RU(CCC(O)ME)(PPH3)2(ETA-C5H5) [J].

BRUCE, MI ;

HINTERDING, P ;

TIEKINK, ERT ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 450 (1-2) :209-218

[6] THE REACTIVITY OF 1-DIETHYLAMINOPROPYNE TOWARDS [FE3(CO)12] AND [FE2(CO)9] - SYNTHESES AND STRUCTURES OF [FE2(CO)6(C50(CH3)2(N(C2H5)2)2)], [FE3(CO)8(C4(CH3)2(N(C2H5)2)2)], [FE2(CO)7(C2(CH3)N(C2H5)2] AND [FE3(CO)8(C4(CH3)2(N(C2H5)2)2)] [J].

CABRERA, E ;

DARAN, JC ;

JEANNIN, Y ;

KRISTIANSSON, O .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 310 (03) :367-390

[7] A TRIAD OF ELECTRON-RICH MU2-ALKYLIDENE COMPLEXES M2(CO)6[MU-CHC(PH)NET2](MU-PPH2)(M=FE,RU,OS) VIA THE ADDITION OF DIETHYLAMINE TO THE ACETYLIDES M2(CO)6(MU2-ETA-2-C=CPH)(MU-PPH2) - SPECTROSCOPIC PROPERTIES AND STRUCTURAL CHEMISTRY [J].

CHERKAS, AA ;

MOTT, GN ;

GRANBY, R ;

MACLAUGHLIN, SA ;

YULE, JE ;

TAYLOR, NJ ;

CARTY, AJ .

ORGANOMETALLICS, 1988, 7 (05) :1115-1121

[8] REACTIVITY PATTERNS FOR MULTISITE-BOUND ACETYLIDES - NUCLEOPHILIC-ATTACK AT THE ALPHA-CARBON IN MU-2-ETA-2-ACETYLIDES - BRIDGING 2-AMINO-1-METALLAPHENETHYLIDENE COMPLEXES VIA ADDITION OF PRIMARY AMINES TO FE2(CO)6(MU-2-ETA-2-C=CPH)(MU-PPH2), RU2(CO)6(MU-2-ETA-2-C=CPH)(MU-PPH2, OS2(CO)6(MU-2-ETA-2-C=CPH(MU-PPH2) [J].

CHERKAS, AA ;

RANDALL, LH ;

TAYLOR, NJ ;

MOTT, GN ;

YULE, JE ;

GUINAMANT, JL ;

CARTY, AJ .

ORGANOMETALLICS, 1990, 9 (05) :1677-1685

[9] POLYNUCLEAR ACETYLIDES - SYNTHESIS, SPECTROSCOPIC FEATURES, AND STRUCTURAL SYSTEMATICS FOR A COMPLETE TRIAD OF MU-2-ETA-2-COMPLEXES - M2(CO)6(MU-2-ETA-2-C=CR)(MU-PPH2)(M=FE,RU,OS) [J].

CHERKAS, AA ;

RANDALL, LH ;

MACLAUGHLIN, SA ;

MOTT, GN ;

TAYLOR, NJ ;

CARTY, AJ .

ORGANOMETALLICS, 1988, 7 (04) :969-977

[10] SYNTHESIS OF MONONUCLEAR, DINUCLEAR AND OLIGOMERIC RIGID-ROD ACETYLIDE COMPLEXES OF RHODIUM, AND THE MOLECULAR-STRUCTURE OF [RH(PME3)4(CC-PARA-C6H4-CC)RH(PME3)4] [J].

FYFE, HB ;

MLEKUZ, M ;

ZARGARIAN, D ;

TAYLOR, NJ ;

MARDER, TB .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) :188-190

← 1 2 3 →