ORGANIC-REACTIONS IN CRYSTALS

被引：19

作者：

TODA, F

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1994年 / 52卷 / 11期

关键词：

D O I：

10.5059/yukigoseikyokaishi.52.923

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By utilizing the phenomenon that molecules move from crystal to crystal quite easily under appropriate conditions, a new type of organic chemistry has been contrived. The combination of the enantioselective molecular movement from racemic guest crystal to chiral host crystal with fractional distillation, leads to a process whereby enantiomeric guest molecules can be separated by distillation. Selective and efficient organic reactions can be carried out by grinding crystals of substrate and reagent.

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页码：923 / 934

页数：12

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