DI-D-FRUCTOSE DIANHYDRIDES FROM THE PYROLYSIS OF INULIN

被引:21
作者
BLIZE, AE [1 ]
MANLEYHARRIS, M [1 ]
RICHARDS, GN [1 ]
机构
[1] UNIV MONTANA,SHAFIZADEH CTR WOOD & CARBOHYDRATE CHEM,MISSOULA,MT 59812
关键词
DI-D-FRUCTOSE DIANHYDRIDES; INULIN; PYROLYSIS OF; FRUCTOSE DIANHYDRIDES; DI-D-; PYROLYSIS;
D O I
10.1016/0008-6215(94)00224-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Inulin was pyrolyzed in air to produce di-D-fructose dianhydrides (DFDAs) in similar to 26% yield, three of which were identified by MS, NMR, and comparison with literature data. The mass spectra of the per-O-trimethylsilyl derivatives of the DFDAs are discussed. A mechanism is proposed for the formation of DFDAs from inulin during pyrolysis.
引用
收藏
页码:31 / 39
页数:9
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