INTRAMOLECULAR SPIN-SPIN EXCHANGE IN CATION RADICALS OF TETRATHIAFULVALENE DERIVATIVES SUBSTITUTED WITH IMINO PYROLIDINE-AND PIPERIDINE-1-OXYLS

被引：45

作者：

SUGIMOTO, T

YAMAGA, S

NAKAI, M

OHMORI, K

TSUJII, M

NAKATSUJI, H

FUJITA, H

YAMAUCHI, J

机构：

[1] KYOTO UNIV, FAC INTEGRATED HUMAN STUDIES, DIV NAT ENVIRONM, KYOTO 606, JAPAN

[2] KYOTO UNIV, GRAD SCH HUMAN ENVIRONM STUDIES, KYOTO 606, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ESR spectra of tetrathiafulvalene (TTF) derivatives substituted with imino pyrolidine- and piperidine-1-oxyls and their cation radicals were investigated. For the neutral TTF's the unpaired electron is localized at the nitroxide group. While, an intramolecular spin-spin exchange albeit weak occurs between the TTF cation radical and the nitroxide radical in the one-electron oxidized TTF's, and the ground spin state of the biradical is a singlet.

引用

页码：1361 / 1364

页数：4

共 9 条

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