KINETICS OF THE LIQUID-PHASE SYNTHESIS AND HYDROLYSIS OF BUTYL LACTATE CATALYZED BY CATION-EXCHANGE RESIN

被引：48

作者：

DASSY, S

WIAME, H

THYRION, FC

机构：

[1] Chemical Engineering Institute, Louvain University, Louvain-La-Nauve, B-1348, 1, Voie Minckelers

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 1994年 / 59卷 / 02期

关键词：

LACTIC ACID; ESTERIFICATION; KINETICS; CATION-EXCHANGE RESIN;

D O I：

10.1002/jctb.280590206

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Esterification of lactic acid with butanol catalysed by cation-exchange resin was carried out in a batch reactor in dioxane and toluene. The reaction rate was found to be first order with respect to catalyst and acid concentrations. The inhibiting effect of water and butanol has been evaluated. The rate data were correlated with a kinetic model based on inhibition by water and butanol.

引用

页码：149 / 156

页数：8

共 10 条

[1] MECHANISMS IN REACTION BETWEEN OLEFINS AND ALCOHOLS CATALYZED BY ION-EXCHANGE RESINS [J].