A NOVEL ETA-7 COORDINATION MODE OF A BENZYL LIGAND IN A CATIONIC ZIRCONIUM COMPLEX

被引:80
作者
PELLECCHIA, C
IMMIRZI, A
PAPPALARDO, D
PELUSO, A
机构
[1] Dipartimento di Fisica, Universitá di Salerno
关键词
D O I
10.1021/om00022a009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Single-crystal X-ray analysis of the ionic complex [(C5Me5)Zr(CH2Ph)2]+[B(CH2Ph)(C6F5)3]- shows that no cation-anion bonding interactions exist, resulting in remarkable structural features in the highly electrophilic ''naked'' cation, including an unprecedented eta7-benzyl coordination.
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页码:3773 / 3775
页数:3
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