CARBON-MONOXIDE AS A BUILDING BLOCK FOR ORGANIC-SYNTHESIS .3. SELECTIVE HYDROCARBONYLATION OF MONOTERPENES TO GIVE POTENTIALLY BIOLOGICALLY-ACTIVE ALDEHYDES

被引：37

作者：

CIPRES, I ^{[1
]}

KALCK, P ^{[1
]}

PARK, DC ^{[1
]}

SEREINSPIRAU, F ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM TOULOUSE,CHIM PROCEDES LAB,EQUIPE CATALYSE & CHIM FINE,118 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 66卷 / 03期

关键词：

D O I：

10.1016/0304-5102(91)80031-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dinuclear rhodium complexes [Rh2(mu-SR)2(CO)2L2], where L = PPh3, P(OPh)3 or P(OMe)3, were shown to be efficient and fully selective precursors for the hydrocarbonylation of limonene, isopulegol, isopulegyl acetate, alpha- and beta-pinenes. This reaction takes place at low pressures (0.5-1.7 MPa) and low temperature (85-degrees-C). The effects of the phosphorus-containing ligands, the solvent, the nature of the monoterpene on the course of the reaction and in particular the regioselectivity of the carbonylation were analyzed.

引用

页码：399 / 407

页数：9

共 18 条

[1] MONOTERPENES - RELATIONSHIP BETWEEN STRUCTURE AND INHIBITION OF GERMINATION
ASPLUND, RO
[J]. PHYTOCHEMISTRY, 1968, 7 (11) : 1995 - &
[2] Chalk A. J., 1988, CATALYSIS ORGANIC RE, P43
[3] CHALK AJ, 1988, FLAVOURS FRAGRANCES, P867
[4] CIPRES I, 1989, THESIS INP TOULOUSE
[5] CORNILS B, 1980, NEW SYNTHESES CARBON, P631
[6] DEDIEU A, 1986, NEW J CHEM, V10, P631
[7] ESCAFFRE P, 1986, THESIS INP TOULOUSE
[8] HIMMELE W, 1978, TETRAHEDRON LETT, V12, P907
[9] HIMMELE W, 1980, ANGEW CHEM INT EDIT, V19, P178
[10] A NOVEL AND EASY WAY TO PREPARE THE RH2(MU-SR)2(CO)4 AND RH2(MU-SR)2(CO)2(PR'3)2 COMPLEXES ON A LARGE-SCALE
KALCK, P
SENOCQ, F
SIANI, M
THOREZ, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 350 (01) : 77 - 80

← 1 2 →