FLUORIDE-PROMOTED COMPETITIVE REACTIONS OF CYANOGEN FLUORIDE, PERFLUOROMETHANIMINE, AND PENTAFLUORO-2-AZAPROPENE

被引：9

作者：

BAUKNIGHT, CW ^{[1
]}

DESMARTEAU, DD ^{[1
]}

机构：

[1] CLEMSON UNIV,HOWARD L HUNTER CHEM LAB,CLEMSON,SC 29634

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1990年 / 112卷 / 02期

关键词：

D O I：

10.1021/ja00158a035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Competitive reactions of cyanogen fluoride (FC≡N), perfluoromethanimine (CF2=NF), and pentafluoro-2-azapropene (CF3N=CF2) were performed by combining pairs of the substrates over KF or CsF. These reactions establish the order of reactivity with fluoride ion as CF2=NF > CF3N=CF2 » F-C≡N. Subsequent reactions of the addition products with fluoride ion, C1F, and Br2/CsF are discussed. Seven new compounds, including a novel diaziridine, were characterized by IR, NMR, MS, and physical properties. © 1990, American Chemical Society. All rights reserved.

引用

页码：728 / 733

页数：6

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