TRANSITION-METAL-CATALYZED METATHESIS OF PHOSPHORUS-PHOSPHORUS DOUBLE-BONDS

被引：32

作者：

DILLON, KB ^{[1
]}

GIBSON, VC ^{[1
]}

SEQUEIRA, LJ ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 23期

关键词：

D O I：

10.1039/C39950002429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

W(PMe(3))(6) is an efficient chloride ion abstracting reagent for the synthesis of RP=PR species from RPCl(2) precursors; moreover, the W(PMe(3))(6)-RPCl(2) solutions catalyse the exchange of the diphosphene PR end-groups via a mechanism closely related to the olefin metathesis process.

引用

页码：2429 / 2430

页数：2

共 10 条

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