STUDIES ON ORGANOLANTHANIDE COMPLEXES .46. SYNTHESIS AND CHARACTERIZATION OF N-CONTAINING RING-LINKED BISCYCLOPENTADIENYL LANTHANIDE AND YTTRIUM CHLORIDES

被引：25

作者：

QIAN, CT

ZHU, DM

机构：

[1] Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 200032 Shanghai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 445卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0022-328X(93)80190-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new title complexes, [CH3N(CH2CH2C5H4)2LnCl]2 (Ln = Y, Yb, Sm, Nd), were synthesized by using amine-linked biscyclopentadiene, CH3N(CH2CH2C5H5)2, as ancillary ligands and fully characterized by elemental analyses, MS, IR and H-1 NMR. Their spectroscopies indicate that these complexes are chloride-bridged dimers and the two amine-linked cyclopentadienyl rings coordinate to one metal in a chelating fashion with intramolecular coordination from the nitrogen atom to the metal.

引用

页码：79 / 84

页数：6

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