VOLTAMMETRIC AND NMR-STUDIES OF A BIS(FERROCENECARBOXAMIDE)-SUBSTITUTED DIAZA 18-CROWN-6 RECEPTOR THAT SIMULTANEOUSLY COMPLEXES AND ELECTROCHEMICALLY RECOGNIZES BOTH CATIONS AND ANIONS

被引：41

作者：

BEER, PD

CHEN, Z

OGDEN, MI

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 02期

关键词：

D O I：

10.1039/ft9959100295

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Voltammetric and NMR investigations of a bis(ferrocenecarboxamide)-substituted diaza 18-crown-6 receptor in an aprotic environment have been carried out. This receptor molecule can complex metal cations or anions individually and can accommodate both a cation and anion. The binding of anions is significantly enhanced by the presence of a bound metal cation, with selectivity for HSO4- over Cl-. The receptor is capable of electrochemically recognising the complexed anions, cations and anion/cation pairs.

引用

页码：295 / 302

页数：8

共 34 条

[1] Albery W. J., 1971, RING DISC ELECTRODES
[2] NEW POCKET IONOPHORES WITH POTENTIAL FOR SIMULTANEOUS CHELATION OF ANIONS AND CATIONS - SYNTHESIS AND SCOPE OF CHELATING PROPERTIES
ARAFA, EA
KINNEAR, KI
LOCKHART, JC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) : 61 - 64
[3] Bard A., 1980, ELECTROCHEMICAL METH
[4] ELECTROCHEMICAL RECOGNITION OF GROUP-1 AND GROUP-2 METAL-CATIONS BY REDOX-ACTIVE IONOPHORES
BEER, PD
CHEN, Z
DREW, MGB
PILGRIM, AJ
[J]. INORGANICA CHIMICA ACTA, 1994, 225 (1-2) : 137 - 144
[5] SELECTIVE ELECTROCHEMICAL RECOGNITION OF THE DIHYDROGEN PHOSPHATE ANION IN THE PRESENCE OF HYDROGEN SULFATE AND CHLORIDE-IONS BY NEW NEUTRAL FERROCENE ANION RECEPTORS
BEER, PD
CHEN, Z
GOULDEN, AJ
GRAYDON, A
STOKES, SE
WEAR, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (24) : 1834 - 1836
[6] NEW POLYAZA AND POLYAMMONIUM FERROCENE MACROCYCLIC LIGANDS THAT COMPLEX AND ELECTROCHEMICALLY RECOGNIZE TRANSITION-METAL CATIONS AND PHOSPHATE ANIONS IN WATER
BEER, PD
CHEN, Z
DREW, MGB
KINGSTON, J
OGDEN, M
SPENCER, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) : 1046 - 1048
[7] A POTASSIUM-SELECTIVE SULFIDE-LINKED REDOX-ACTIVE FERROCENE IONOPHORE THAT EXHIBITS EXTRAORDINARY ELECTROCHEMICAL RECOGNITION BEHAVIOR
BEER, PD
DANKS, JP
HESEK, D
MCALEER, JF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (23) : 1735 - 1737
[8] A NEW BIPYRIDINIUM BIS BENZO CROWN-ETHER LIGAND WHOSE REDOX PROPERTIES ARE DEPENDENT UPON COMPLEXED CATION-INDUCED CONFORMATIONAL SWITCHING EFFECTS
BEER, PD
CHEN, Z
GRIEVE, A
HAGGITT, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) : 2413 - 2414
[9] ANION RECOGNITION BY NOVEL RUTHENIUM(II) BIPYRIDYL CALIX[4]ARENE RECEPTOR MOLECULES
BEER, PD
CHEN, Z
GOULDEN, AJ
GRIEVE, A
HESEK, D
SZEMES, F
WEAR, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (10) : 1269 - 1271
[10] AMMONIUM REDOX-RESPONSIVE RECEPTORS CONTAINING MULTIPLE FERROCENE AND QUINONE REDOX-ACTIVE CENTERS ATTACHED TO DI-AZA AND TRI-AZA CROWN-ETHER MACROCYCLES
BEER, PD
CROWE, DB
OGDEN, MI
DREW, MGB
MAIN, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (14): : 2107 - 2116

← 1 2 3 4 →