STEREOELECTRONIC EFFECTS AT OXYGEN - A VERY LARGE EFFECT ON THE HYDROLYSIS OF A CONFORMATIONALLY LOCKED ACETAL - IMPLICATIONS FOR BETA-GLYCOSIDASE MECHANISMS

被引：37

作者：

BRIGGS, AJ ^{[1
]}

EVANS, CM ^{[1
]}

GLENN, R ^{[1
]}

KIRBY, AJ ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1983年 / 11期

关键词：

D O I：

10.1039/p29830001637

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：1637 / 1640

页数：4

共 30 条

[1]

[Anonymous], 1971, PURE APPL CHEM

[2]

BANERJEE SK, 1975, J BIOL CHEM, V250, P4355

[3] THE SN2-SN1 SPECTRUM .3. SOLVOLYSES OF SECONDARY AND TERTIARY ALKYL SULFONATES IN FLUORINATED ALCOHOLS - FURTHER EVIDENCE FOR THE SN2 (INTERMEDIATE) MECHANISM [J].

BENTLEY, TW ;

BOWEN, CT ;

MORTEN, DH ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5466-5475

[4] STEREOELECTRONIC EFFECTS AT OXYGEN - THE HYDROLYSIS OF 2-ARYLOXY-TRANS-1-OXADECALINS [J].

CHANDRASEKHAR, S ;

KIRBY, AJ ;

MARTIN, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1983, (11) :1619-1626

[5] SPONTANEOUS HYDROLYSIS OF ACETALS - SENSITIVITY TO LEAVING GROUP [J].

CRAZE, GA ;

KIRBY, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (04) :354-356

[6] BIMOLECULAR NUCLEOPHILIC-SUBSTITUTION ON AN ACETAL [J].

CRAZE, GA ;

KIRBY, AJ ;

OSBORNE, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (04) :357-369

[7] SOLVOLYSIS OF 1-CHLOROBICYCLO[3.3.1]NONANE [J].

DAUBEN, WG ;

POULTER, CD .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (03) :1237-&

[8] A VERY LARGE STEREOELECTRONIC EFFECT ON ACETAL CLEAVAGE [J].

EVANS, CM ;

GLENN, R ;

KIRBY, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (17) :4706-4707

[9] ABINITIO CALCULATIONS AND C-13 NMR-STUDY ON THE METHOXYMETHYL CATION [J].

FARCASIU, D ;

HORSLEY, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (15) :4906-4911

[10] RESOLUTION OF THE INDIVIDUAL STEPS IN THE REACTION OF LYSOZYME WITH THE TRIMER AND HEXAMER OF N-ACETYL-D-GLUCOSAMINE AT SUBZERO TEMPERATURES [J].

FINK, AL ;

HOMER, R ;

WEBER, JP .

BIOCHEMISTRY, 1980, 19 (04) :811-820

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