THE PREPARATION OF (Z)-2-LITHIO-ORTHO-STYRYLLITHIUM VIA AN ORTHO-DIRECTED LITHIATION

被引:10
作者
ASHE, AJ
SAVLA, PM
机构
[1] Department of Chemistry, The University of Michigan, Ann Arbor
关键词
D O I
10.1016/0022-328X(93)83263-U
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Lithiation of (Z)-2-lithiostyrene with t-butyllithium/TMEDA pentane led directly to (Z)-2-lithio-ortho-styryllithium. Subsequent treatment of this dilithio compound with difunctional electrophiles allowed the preparation of a variety of benzo[b]heteroles.
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页码:1 / 3
页数:3
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