MOLECULAR RECOGNITION OF BARBITURATES BY DIAMINOTRIAZINE FUNCTIONALIZED MONOLAYERS

被引:54
作者
HONDA, Y [1 ]
KURIHARA, K [1 ]
KUNITAKE, T [1 ]
机构
[1] KYUSHU UNIV, FAC ENGN, DEPT ORGAN SYNTH, FUKUOKA 812, JAPAN
关键词
D O I
10.1246/cl.1991.681
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Diaminotriazine functionalized amphiphiles were synthesized to form stable monolayers at the air-water interface. Combined examination of FT-IR, ESCA, and reflection absorption spectroscopies confirmed specific binding of barbituric acid and thiobarbituric acid to the monolayer, due to hydrogen bonding between the diaminotriazine head of amphiphiles and the imide moiety of barbiturates.
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页码:681 / 684
页数:4
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