TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES

被引:92
作者
MIURA, K [1 ]
TANIGUCHI, M [1 ]
NOZAKI, K [1 ]
OSHIMA, K [1 ]
UTIMOTO, K [1 ]
机构
[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,SAKYO KU,KYOTO 606,JAPAN
关键词
D O I
10.1016/S0040-4039(00)97073-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of perfluoroalkyl iodides with silyl enol ethers mediated by Et3B in the presence of a base provides perfluoroalkylated silyl enol ethers. Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords β-perfluoroalkyl ketones in good yields. © 1990.
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页码:6391 / 6394
页数:4
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