TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES

被引：92

作者：

MIURA, K ^{[1
]}

TANIGUCHI, M ^{[1
]}

NOZAKI, K ^{[1
]}

OSHIMA, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,SAKYO KU,KYOTO 606,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97073-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of perfluoroalkyl iodides with silyl enol ethers mediated by Et3B in the presence of a base provides perfluoroalkylated silyl enol ethers. Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords β-perfluoroalkyl ketones in good yields. © 1990.

引用

页码：6391 / 6394

页数：4

共 6 条

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[4] A NEW METHOD FOR THE PREPARATION OF ALPHA-(PERFLUOROALKYL) CARBONYL AND GAMMA-(PERFLUOROALKYL)-ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
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[5] UMEMOTO T, 1990, TETRAHEDRON LETT, V31, P3579
[6] TRAPPING OF TRIFLUOROMETHYL RADICAL WITH ENOLACETATE AND INSITU GENERATED ENOL
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[J]. CHEMISTRY LETTERS, 1988, (05) : 853 - 854

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