STRUCTURE OF CIS-DICHLOROBIS(3,5-DIPHENYLPYRAZOLE)PLATINUM(II) TETRAHYDROFURAN SOLVATE - A PLATINUM COMPLEX CONTAINING 2 PYRAZOLE LIGANDS

被引：11

作者：

RAPTIS, RG

FACKLER, JP

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

[2] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190012823

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[PtCl2(C15H12N2)2].C4H8O, M(r) = 778.7, triclinic, P1BAR, a = 9.954 (3), b = 11.579 (3), c = 15.141 (3) angstrom, alpha = 70.30 (2), beta = 75.79 (2), gamma = 78.54 (2)-degrees, V = 1579.8 (7) angstrom 3, Z = 2, D(x) = 1.637 Mg m-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 4.69 mm-1, F(000) = 767.8, T = 298 K. The structure consists of a square-planar platinum(II) complex containing two chloride and two 3,5-diphenylpyrazole ligands in cis geometry along with an interstitial molecule of tetrahydrofuran. Convergence to final conventional R values of R = 0.0388 and wR = 0.0406 was obtained using 331 variable parameters and 3476 reflections with F(o)2 > 3-sigma(F(o)2).

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页码：1180 / 1183

页数：4

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