A HIGH-RESOLUTION C-13 SOLID-STATE NMR-STUDY OF MESO-TETRAPHENYLPORPHYRIN AND ITS ZINC(II) COMPLEX

被引：4

作者：

ROCHA, J

KOLODZIEJSKI, W

CAVALEIRO, JAS

KLINOWSKI, J

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV AVEIRO,DEPT CHEM,P-3800 AVEIRO,PORTUGAL

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1992年 / 25卷 / 03期

关键词：

MESO-TETRAPHENYLPORPHYRIN; ZN(II) COMPLEX; SOLID STATE C-13 NMR;

D O I：

10.1080/00958979209409192

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

High-resolution 13C solid-state NMR spectra of meso-tetraphenyIporphyrin (TPP) and its zinc(II) complex (ZnTPP) are assigned by reference to low-temperature solution NMR results and using 1H- 13C cross-polarization magic-angle-spinning (CP/MAS). The splittings of the signals from pyrrole carbons in TPP are attributed to kinetic solid-state effects involved in the migration of the central hydrogen atom. © 1992, Taylor & Francis Group, LLC. All rights reserved.

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页码：205 / 210

页数：6

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