ECLIPSED COFACIAL DIMERS OF METAL-COMPLEXES CONTAINING D(7)-D(7) AND D(8)-D(8) METAL BONDS - CRYSTAL-STRUCTURE OF BIS[BIS((PHENANTHRENE-9,10-DIAMIN)YLATO)COBALT(II)] AND BIS[((2,3-DICYANOETHENEDIAMIN)YLATO)DICARBONYLRHODIUM(I)]

被引：15

作者：

CHERN, SS ^{[1
]}

LIAW, MC ^{[1
]}

PENG, SM ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000359

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel crystal structures containing the eclipsed conformation of diaminylato type ligands and metal-metal bonds are described; bis[bis{(phenanthrene-9,10-diamin)ylato}cobalt(II)] contains a Co(II)-Co(II) bond [2.689(1) angstrom] and two delta bonds between two pairs of parallel (phenanthrene-9,10-diamin)ylato ligands and bis[{(2,3-dicyanoethenediamin)ylato}dicarbonylrhodium(I)] contains a Rh(I)-Rh(I) bond [2.833(2) angstrom] and one delta bond between a pair of parallel (2,3-dicyanoethenediamin)ylato ligands.

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页码：359 / 361

页数：3

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