IMPORTANCE OF STERIC EFFECTS IN THE [4+2] CYCLOADDITION OF 5-SUBSTITUTED PENTAMETHYLCYCLOPENTADIENES

被引：23

作者：

ADAM, W

JACOB, U

PREIN, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000839

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentamethylcyclopentadienes with a carbon substituent (X = Pr-i, Et, CH2OH, CHO) at the C-5 position give anti cycloadducts with a variety of dienophiles, which establishes the importance of steric effects in the [4 + 2] cycloaddition of these plane-nonsymmetric dienes.

引用

页码：839 / 840

页数：2