CATALYTIC ASYMMETRIC-SYNTHESIS OF ALPHA-METHYLENE-BETA-HYDROXY-KETONES

被引：52

作者：

BARRETT, AGM

KAMIMURA, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001755

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Condensation of an alpha,beta-unsaturated ketone, an aldehyde and trimethylsilyl phenyl sulfide Or selenide, catalysed by a chiral (acyloxy)borane, and subsequent oxidative elimination gives the title adducts in high enantiomeric excess.

引用

页码：1755 / 1756

页数：2

共 21 条

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