ENTHALPY CHANGE FOR THE S-TRANS TO S-CIS CONFORMATIONAL EQUILIBRIUM IN 2-METHYL-1,3-BUTADIENE (ISOPRENE), AS STUDIED BY HIGH-TEMPERATURE ULTRAVIOLET-ABSORPTION SPECTROSCOPY

被引：23

作者：

MUI, PW ^{[1
]}

GRUNWALD, E ^{[1
]}

机构：

[1] BRANDEIS UNIV,DEPT CHEM,WALTHAM,MA 02154

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1984年 / 88卷 / 25期

关键词：

D O I：

10.1021/j150669a056

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

引用

页码：6340 / 6344

页数：5

共 24 条

[1] CONFORMATIONS OF CONJUGATED HYDROCARBONS .1. SPECTROSCOPIC AND THERMODYNAMIC STUDY OF BUTA-1,3-DIENE AND 2-METHYLBUTA-1,3-DIENE (ISOPRENE) [J].

COMPTON, DAC ;

GEORGE, WO ;

MADDAMS, WF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (14) :1666-1671

[2] CONFORMATIONAL STUDIES OF 1,3-DIENES [J].

DEVAQUET, AJP ;

TOWNSHEND, RE ;

HEHRE, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (14) :4068-4076

[3] STERIC EFFECTS IN CONJUGATED SYSTEMS .6. S-CIS-S-TRANS ENERGY DIFFERENCES AND BARRIER HEIGHTS TO INTERNAL-ROTATION AROUND CSP2-CSP2 BONDS IN MONOMETHYLATED BUTADIENES AND ACROLEINS [J].

DODZIUK, H .

JOURNAL OF MOLECULAR STRUCTURE, 1974, 20 (02) :317-319

[4] AB-INITIO SCF AND CL CALCULATIONS ON BARRIER TO INTERNAL-ROTATION OF 1,3-BUTADIENE [J].

DUMBACHER, B .

THEORETICA CHIMICA ACTA, 1972, 23 (04) :346-+

[5]

DZHESSATI S, 1968, VESTN MOSK U KHIM, V5, P19

[6]

DZHESSATI S, 1965, ZH STRUCT KHIM, V6, P465

[7] TEMPERATURE-DEPENDENCE OF ABSORPTION-SPECTRA FOR ORBITALLY ALLOWED ELECTRONIC-TRANSITIONS OF POLYATOMIC-MOLECULES [J].

GRUNWALD, E .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (23) :3409-3415

[8] Studies in gaseous polymerizations [J].

Harkness, JB ;

Kistiakowsky, GB ;

Mears, WH .

JOURNAL OF CHEMICAL PHYSICS, 1937, 5 (09) :682-694

[9] BARRIER TO INTERNAL ROTATION OF METHYL GROUP AND IDENTIFICATION OF TRANS FORM OF ISOPRENE [J].

HSU, SL ;

KEMP, MK ;

POCHAN, JM ;

BENSON, RC ;

FLYGARE, WH .

JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (03) :1482-&

[10]

KAVANASAEBO K, 1984, J MOL STRUC-THEOCHEM, V106, P259

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