ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON .2. NUMERICAL-CALCULATIONS OF THE PROFILES OF THE ELECTRON IN WATER AND METHANOL AT 300-K

被引：34

作者：

ABRAMCZYK, H ^{[1
]}

KROH, J ^{[1
]}

机构：

[1] TECH UNIV LODZ,INST APPL RADIAT CHEM,WROBLEWSKIEGO 15,PL-93590 LODZ,POLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 16期

关键词：

D O I：

10.1021/j100169a020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption band profiles of the solvated electrons in the spectral range 0.62-2.48 eV were calculated in terms of the theory presented in our previous paper. We considered the influence of the environment, the effect of fluctuations of the energy potential shape, and the band profiles as a function of the coupling strength with intramolecular vibrations of the solvent. The theory gives good agreement with experiment for the electron solvated in water and alcohols at 300 K.

引用

页码：6155 / 6159

页数：5

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