ANALYSIS OF FULLERENES BY REVERSED-PHASE HIGHPERFORMANCE LIQUID-CHROMATOGRAPHY

被引：10

作者：

HARWOOD, JJ ^{[1
]}

MAMANTOV, G ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

JOURNAL OF CHROMATOGRAPHY A | 1993年 / 654卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9673(93)83376-4

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Chromatographic separation of fullerenes was achieved with a conventional reversed-phase analytical system. A tetrahydrofuran-acetonitrile mobile phase (60:40) (1.0 ml/min) used with a 25 cm ODS column separates C-60 and C-70 with a resolution of 6.4 and an analysis time of 11.4 min. This method is convenient and offers sufficient resolving power to be applied to the analysis of a variety of fullerenes and fullerene reaction product mixtures. The mobile phase allows use of the sensitive ultraviolet absorbance bands of fullerenes in detection. The method is compared with other reversed-phase methods for analysis of fullerene mixtures.

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页码：315 / 318

页数：4

相关论文

共 17 条

[1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70 [J].

AJIE, H ;

ALVAREZ, MM ;

ANZ, SJ ;

BECK, RD ;

DIEDERICH, F ;

FOSTIROPOULOS, K ;

HUFFMAN, DR ;

KRATSCHMER, W ;

RUBIN, Y ;

SCHRIVER, KE ;

SENSHARMA, D ;

WHETTEN, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8630-8633

[2]

BAUM R, 1992, CHEM ENG NEWS, V70, P43

[3] CHARACTERIZATION OF C60 AND C70 CLUSTERS [J].

COX, DM ;

BEHAL, S ;

DISKO, M ;

GORUN, SM ;

GREANEY, M ;

HSU, CS ;

KOLLIN, EB ;

MILLAR, J ;

ROBBINS, J ;

ROBBINS, W ;

SHERWOOD, RD ;

TINDALL, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :2940-2944

[4] CONTRIBUTION TO THE ISOLATION AND CHARACTERIZATION OF BUCKMINSTERFULLERENES [J].

DIACK, M ;

HETTICH, RL ;

COMPTON, RN ;

GUIOCHON, G .

ANALYTICAL CHEMISTRY, 1992, 64 (18) :2143-2148

[5] ISOLATION OF C76, A CHIRAL (D2) ALLOTROPE OF CARBON [J].

ETTL, R ;

CHAO, I ;

DIEDERICH, F ;

WHETTEN, RL .

NATURE, 1991, 353 (6340) :149-153

[6] OPTIMIZATION OF SOLVENT STRENGTH AND SELECTIVITY FOR REVERSED-PHASE LIQUID-CHROMATOGRAPHY USING AN INTERACTIVE MIXTURE-DESIGN STATISTICAL TECHNIQUE [J].

GLAJCH, JL ;

KIRKLAND, JJ ;

SQUIRE, KM ;

MINOR, JM .

JOURNAL OF CHROMATOGRAPHY, 1980, 199 (OCT) :57-79

[7] ORGANIC-CHEMISTRY OF C60 (BUCKMINSTERFULLERENE) - CHROMATOGRAPHY AND OSMYLATION [J].

HAWKINS, JM ;

LEWIS, TA ;

LOREN, SD ;

MEYER, A ;

HEATH, JR ;

SHIBATO, Y ;

SAYKALLY, RJ .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (26) :6250-6252

[8] SEPARATION AND IDENTIFICATION OF FULLERENES BY LIQUID-CHROMATOGRAPHY [J].

JINNO, K ;

UEMURA, T ;

NAGASHIMA, H ;

ITOH, K .

CHROMATOGRAPHIA, 1993, 35 (1-2) :38-44

[9]

KLUTE RC, 1992, J CHROMATOGR SCI, V30, P48

[10] EFFICIENT PREPARATIVE SEPARATION OF C-60 AND C-70 - GEL-PERMEATION CHROMATOGRAPHY OF FULLERENES USING 100-PERCENT TOLUENE AS MOBILE PHASE [J].

MEIER, MS ;

SELEGUE, JP .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (06) :1924-1926