STATISTICAL GROUP TRANSFER COPOLYMERIZATION - MONOMER REACTIVITY RATIOS FOR ALLYL METHACRYLATE AND NORMAL-BUTYL METHACRYLATE

被引：13

作者：

CATALGILGIZ, H

UYANIK, N

ERBIL, C

机构：

[1] Istanbul Teknik Üniversitesi, Fen-Edebiyat Fakültesi, 80626 Maslak, Istanbul

来源：

POLYMER | 1992年 / 33卷 / 03期

关键词：

STATISTICAL COPOLYMERIZATION; GROUP TRANSFER POLYMERIZATION; REACTIVITY RATIO; KELEN-TUDOS METHOD; FINEMAN-ROSS METHOD;

D O I：

10.1016/0032-3861(92)90747-K

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris(dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tudos and Fineman-Ross methods. The reactivity ratios were found to be r(AMA) = 2.35, r(BMA) = 0.08 (Kelen-Tudos) and r(AMA) = 2.37, r(BMA) = 0.08 (Fineman-Ross).

引用

页码：655 / 656

页数：2

共 10 条

[1] GROUP-TRANSFER COPOLYMERIZATION
CATALGIL, H
JENKINS, AD
[J]. EUROPEAN POLYMER JOURNAL, 1991, 27 (07) : 651 - 652
[2] LINEAR METHOD FOR DETERMINING MONOMER REACTIVITY RATIOS IN COPOLYMERIZATION
FINEMAN, M
ROSS, SD
[J]. JOURNAL OF POLYMER SCIENCE, 1950, 5 (02): : 259 - 262
[3] JENKINS AD, 1988, POLYM BULL, V20, P97
[4] ANALYSIS OF LINEAR METHODS FOR DETERMINING COPOLYMERIZATION REACTIVITY RATIOS .1. NEW IMPROVED LINEAR GRAPHIC METHOD
KELEN, T
TUDOS, F
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (01): : 1 - 27
[5] MARK HF, 1985, ENCY POLYM SCI ENG, V2, P1
[6] MARK HF, 1986, ENCY POLYM SCI, V4, P554
[7] GROUP TRANSFER AND ANIONIC-POLYMERIZATION - A CRITICAL COMPARISON
MULLER, AHE
[J]. MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 : 87 - 104
[8] COPOLYMER ANALYSIS BY UV SPECTROSCOPY
RAMELOW, U
BAYSAL, BM
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (07) : 5865 - 5882
[9] GROUP TRANSFER POLYMERIZATION - POLYMERIZATION OF ACRYLIC-MONOMERS
SOGAH, DY
HERTLER, WR
WEBSTER, OW
COHEN, GM
[J]. MACROMOLECULES, 1987, 20 (07) : 1473 - 1488
[10] GROUP-TRANSFER POLYMERIZATION .1. A NEW CONCEPT FOR ADDITION POLYMERIZATION WITH ORGANO-SILICON INITIATORS
WEBSTER, OW
HERTLER, WR
SOGAH, DY
FARNHAM, WB
RAJANBABU, TV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (17) : 5706 - 5708

← 1 →