CHARGE-EXCHANGE REACTIONS OF STATE-SELECTED SULFUR IONS WITH OCS

被引：4

作者：

APPLING, JR ^{[1
]}

HARBOL, MR ^{[1
]}

EDGINGTON, RA ^{[1
]}

GOREN, AC ^{[1
]}

LAI, S ^{[1
]}

机构：

[1] TRANSYLVANIA UNIV,DEPT CHEM,LEXINGTON,KY 40508

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 184卷 / 5-6期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(91)80013-N

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sulfur ions in the 2D(J)-degrees excited state are observed to charge exchange with OCS molecules. These excited ions are created using resonantly enhanced multiphoton ionization of sulfur atoms generated from photodissociation of parent OCS. Evidence for ionic state-selection is documented with photoelectron spectroscopy. Ground state sulfur ions produced via two-photon autoionization through the 3s23p35p 1P1 state at 87624 cm-1 do not exhibit charge exchange reactions under identical conditions.

引用

页码：428 / 432

页数：5

共 10 条

[1]

APPLING JR, UNPUB

[2]

ARNOLD F, 1982, ATMOSPHERIC CHEM, P273

[3] RATE COEFFICIENTS FOR S(1D) REMOVAL AT 300-K [J].