ELECTROCATALYTIC OXIDATION OF METHANOL ON A GLASSY-CARBON ELECTRODE MODIFIED BY NICKEL-HYDROXIDE FORMED BY EX-SITU CHEMICAL PRECIPITATION

被引：211

作者：

TARASZEWSKA, J

ROSLONEK, G

机构：

[1] Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 364卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)02919-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The properties of a glassy carbon (GC) electrode modified by nickel hydroxide formed by ex situ chemical precipitation were studied by cyclic voltammetry in alkaline solutions; and compared with the properties of the GC electrode modified by nickel tetraazamacrocyclic complexes. It was found that the GC/Ni(OH)2 modified electrode acts as an effective catalyst for the oxidation of methanol.

引用

收藏

页码：209 / 213

页数：5

相关论文

共 16 条

[1]

Bode H., 1966, ELECTROCHIM ACTA, V11, P1079, DOI DOI 10.1016/0013-4686(66)80045-2

[2] APPLICATION OF THE HYDROUS OXIDE MEDIATION MODEL OF ELECTROCATALYSIS TO REACTIONS AT NOBLE-METAL ANODES IN BASE .1. PT, PD AND RH [J].

BURKE, LD ;

ODWYER, KJ .

ELECTROCHIMICA ACTA, 1990, 35 (11-12) :1821-1827

[3] STABILITY OF THE COMPLEX OF NICKEL(II) WITH CYCLAM [J].

EVERS, A ;

HANCOCK, RD .

INORGANICA CHIMICA ACTA, 1989, 160 (02) :245-248

[4] KINETICS AND MECHANISM OF OXIDATION OF AMINES AND ALCOHOLS AT OXIDE-COVERED NICKEL, SILVER, COPPER, AND COBALT ELECTRODES [J].

FLEISCHM.M ;

PLETCHER, D ;

KORINEK, K .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (10) :1396-&

[5] OXIDATION OF ORGANIC COMPOUNDS AT A NICKEL ANODE IN ALKALINE SOLUTION [J].

FLEISCHMANN, M ;

KORINEK, K ;

PLETCHER, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1971, 31 (01) :39-+

[6] INSITU UV VISIBLE REFLECTANCE SPECTROSCOPIC INVESTIGATION OF THE NICKEL ELECTRODE ALKALINE-SOLUTION INTERFACE [J].

HAHN, F ;

BEDEN, B ;

CROISSANT, MJ ;

LAMY, C .

ELECTROCHIMICA ACTA, 1986, 31 (03) :335-342

[7] ELECTROCATALYTIC OXIDATION OF ORGANIC-COMPOUNDS ON NOBLE-METALS IN AQUEOUS-SOLUTION [J].

LAMY, C .

ELECTROCHIMICA ACTA, 1984, 29 (11) :1581-1588

[8]

Mc Breen J., 1990, MODERN ASPECTS ELECT, V21

[9] THE OXIDATION OF SMALL ORGANIC-MOLECULES - A SURVEY OF RECENT FUEL-CELL RELATED RESEARCH [J].

PARSONS, R ;

VANDERNOOT, T .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 257 (1-2) :9-45

[10] ON THE OXIDATION OF ALCOHOLS AND AMINES AT NICKEL-OXIDE ELECTRODES - MECHANISTIC ASPECTS [J].

ROBERTSON, PM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01) :97-104