BIS[TRIS(2-HYDROXYETHYL)AMINE]NICKEL(II) CHLORIDE

被引：18

作者：

ICBUDAK, H ^{[1
]}

YILMAZ, VT ^{[1
]}

HOWIE, RA ^{[1
]}

ANDAC, O ^{[1
]}

OLMEZ, H ^{[1
]}

机构：

[1] UNIV ABERDEEN,DEPT CHEM,ABERDEEN AB9 2UE,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270195001600

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of bis(2,2',2 '' -nitrilotriethanol-N,O,O')nickel(II) chloride, [Ni(C6H15NO3)(2)]Cl-2, has been determined from X-ray intensity data. The structure consists of an [Ni(C6H15NO3)(2)](2+) cation and two Cl- anions. The central Ni atom in the cation is coordinated by two 2,2/,2 ''-nitrilotriethanol ligands, with bonds to four O atoms and two N atoms resulting in a distorted octahedral environment. The N atoms occupy trans positions and the O3 atom does not coordinate the Ni atom. The Cl anions form three strong intermolecular hydrogen bonds with the hydroxy H atoms of different cations.

引用

页码：1759 / 1761

页数：3

共 11 条

[1] DICHLOROTETRAKIS(PYRIDINE)NICKEL(II) [J].