A CHEMICAL INVESTIGATION OF SHALE OIL AGING

被引：7

作者：

FOOKES, CJR

WALTERS, CK

机构：

[1] CSIRO Division of Fuel Technology, Menai, NSW 2234

来源：

FUEL | 1990年 / 69卷 / 09期

关键词：

ageing; oxidation; shale oil;

D O I：

10.1016/0016-2361(90)90063-V

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Chemical changes resulting from exposure of Stuart and Nagoorin (Queensland, Australia) Fischer assay oils to oxygen at 45 °C for 4000 h were investigated by n.m.r., g.c.-m.s. and potentiometric titration techniques. The most significant reactions, which were all accelerated by visible light, involved oxidation of alkenes, phenols and pyrroles. A possible mechanism of gum formation is given. © 1990.

引用

页码：1105 / 1108

页数：4

共 8 条

[1]

BATTS BD, UNPUB ENERGY FUELS

[2]

BOLAND JL, 1950, T FARADAY SOC, V46, P358

[3] SEPARATION OF LIQUID FOSSIL-FUELS INTO ACID, BASE AND NEUTRAL CONCENTRATES .1. AN IMPROVED NONAQUEOUS ION-EXCHANGE METHOD [J].