A RECHARGEABLE BATTERY EMPLOYING A REDUCED POLYACETYLENE ANODE AND A TITANIUM DISULFIDE CATHODE

被引:38
作者
CAJA, J [1 ]
KANER, RB [1 ]
MACDIARMID, AG [1 ]
机构
[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104
关键词
ELECTROCHEMISTRY - ELECTRODES - Plastics Applications - TITANIUM COMPOUNDS - Electrochemistry;
D O I
10.1149/1.2115400
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Novel rechargeable battery cells have been constructed using a reduced form of the conducting organic polymer, polyacetylene, as the anode, the inorganic intercalating material, titanium disulfide as the cathode, and either 1. 0M LiClO//4 in the THF or 1. 0M NaPF//6 in THF as the nonaqueous electrolyte. A feasibility study of the cells is described. It includes constant current discharge characteristics, stability, and rechargeability. The cells exhibited good stability and reversibility. Their performance was cathode limited, owing to the method used for fabricating the TiS//2 electrode.
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页码:2744 / 2750
页数:7
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