FINAL-STATE DISTRIBUTIONS FROM UNIMOLECULAR REACTIONS - IMPLICATIONS OF A GENERAL THEOREM

被引：10

作者：

KLOTS, CE

机构：

[1] Chemical Physics Section, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6125

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 06期

关键词：

D O I：

10.1021/j100006a017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A recently derived theorem connects the final state distribution following unimolecular decomposition of an isolated molecule with that which one might measure in a heat bath. The ramifications of this relation and technical aspects of its implementation are examined here. Useful relations for rotational and kinetic energy distributions are derived. Expressions for the energy and angular momentum dependence of branching ratios are presented.

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页码：1748 / 1753

页数：6

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