3,3,3-TRIFLUORO-2-ISOCYANOPROPIONATES, NEW VERSATILE BUILDING-BLOCKS FOR THE INTRODUCTION OF TRIFLUOROMETHYL GROUPS INTO ORGANIC-MOLECULES

被引：6

作者：

BURGER, K

SCHIERLINGER, C

MUTZE, K

机构：

[1] Organisch-Chemisches Institut der Technischen Universität München, D-85747 Garching

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80487-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

alpha-Trifluoromethyl-substituted alpha-amino acid esters 1 give N-formyl alpha-trifluoromethyl alpha-amino acid esters 2 on reaction with formic acid/acetic anhydride. 3,3,3-Trifluoro-2-isocyanopropionates 3 are obtained from 2 upon treatment with diphosgene/triethylamine.

引用

页码：149 / 152

页数：4

共 20 条

[1]

Banks R. E., 1979, ORGANOFLUORINE CHEM

[2]

BURGER K, 1991, Z NATURFORSCH B, V46, P361

[3] SYNTHETIC POTENTIAL OF TRIFLUOROMETHYL SUBSTITUTED TIN HETEROCYCLES [J].