NEW SYNTHESIS OF 10-ALKOXY-5H-DIBENZ[B,F]AZEPINES

被引：9

作者：

HAASZ, F

GALAMB, V

机构：

[1] Alkaloida Chemical Company Ltd.

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 05期

关键词：

Azepines - Epoxy - Sodium hypochlorites - Vinyl ethers;

D O I：

10.1080/00397919408012646

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 5-acetyl-5H-dibenz[b,f]azepines with sodium-hypochlorite led to the 5-acetyl-10,11-epoxy-10,11-dihydro-5H-dibenz[b,f] azepine (1). The lithium iodide induced rearrangement of 1 gave the keton 2 which was reacted with trialkyl-orthoformates leading to the vinyl ethers 3a,b.

引用

页码：683 / 687

页数：5