CHARACTERIZATION BY MICROWAVE SPECTROSCOPY OF A TRANSIENT HYDROGEN-BONDED COMPLEX OF OXIRANE AND HYDROGEN-CHLORIDE ISOLATED IN A PULSED JET

被引：13

作者：

LEGON, AC

REGO, CA

机构：

[1] Department of Chemistry, University of Exeter, Exeter, EX4 4QD, Stocker Road

[2] Department of Chemistry, University College London, London, WC 1HOAJ

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 01期

关键词：

D O I：

10.1002/anie.199000721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intermediate of the HX‐initiated ring‐opening of oxirane could be characterized in the gas phase by microwave spectroscopy for the case X = Cl. Oxirane and HCL could only be mixed at the time of expansion so as to hinder ring‐opening by immediate “freezingin” of the complex. The structure proposed on the right with ϕ = 77° was derived from an analysis of the rotation spectrum. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：72 / 73

页数：2

共 13 条

[1] THEORETICAL ABINITIO STUDY OF THE REACTION OF FORMATION OF 2-FLUOROETHANOL FROM OXIRANE AND HF [J].