NITRENIUM IONS IN N-CHLORO-ALPHA-AMINO ACIDS DECOMPOSITION

被引：14

作者：

ARMESTO, XL ^{[1
]}

CANLE, M ^{[1
]}

LOSADA, M ^{[1
]}

SANTABALLA, JA ^{[1
]}

机构：

[1] UNIV LA CORUNA, FAC CIENCIAS, DEPT QUIM FUNDAMENTAL & IND, A ZAPATEIRA, E-15071 LA CORUNA, SPAIN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1993年 / 25卷 / 01期

关键词：

D O I：

10.1002/kin.550250102

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article deals with the kinetics of decomposition of four isomers: N -Cl-(L)-2-Aminohexanoic acid, N - Cl-(L)-Leucine, N - Cl-(L)-Isoleucine, and N - Cl-(L)-tert-Leucine, in mild acid and basic aqueous solution. An alternative mechanism for this process which takes place through a nitrenium-like ion transition state is proposed. This mechanism is in consonance with the experimental data and with those available from the literature.

引用

页码：1 / 8

页数：8

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