A STUDY OF BENZENE ELECTROPOLYMERIZATION IN THE BU4NBF4-OLEUM-CH2CL2 SYSTEM

被引：12

作者：

GOLDENBERG, LM

NAZAROVA, IB

EFIMOV, ON

LYUBOVSKAYA, RN

ROSCHUPKINA, OS

TITKOV, AN

机构：

[1] U.S.S.R. Academy, Sciences Institute of Chemical Physics

来源：

SYNTHETIC METALS | 1991年 / 44卷 / 02期

关键词：

D O I：

10.1016/0379-6779(91)91828-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Benzene electropolymerization in the Bu4NBF4-oleum-CH2Cl2 system has been investigated. It was shown that on Pt, Ni, Al and Ti electrodes flexible films of poly(p-phenylene) could be obtained. Studies of the polymerization process under different electrochemical conditions are presented. Oleum addition removes water traces and promotes film doping. Oleum passivates the surface of ventile metals (Al, Ti). However, the oxide film formed does not prevent benzene oxidation. In addition, the data on IR spectroscopy and scanning electron microscopy are discussed.

引用

页码：133 / 142

页数：10

共 19 条

[1] A NEW METHOD FOR OBTAINING POLYPARAPHENYLENE FILMS BY ELECTROCHEMICAL OXIDATION OF (BENZENE-SBF5) PI-COMPLEXES IN SO2 MEDIUM [J].