AQUEOUS HIGH-TEMPERATURE CHEMISTRY OF CARBOCYCLES AND HETEROCYCLES .11. AQUATHERMOLYSIS OF ARYLAMINES IN THE PRESENCE AND ABSENCE OF SODIUM BISULFITE

被引：10

作者：

KATRITZKY, AR ^{[1
]}

MURUGAN, R ^{[1
]}

BALASUBRAMANIAN, M ^{[1
]}

SISKIN, M ^{[1
]}

机构：

[1] EXXON RES & ENGN CO,CORP RES SCI,ANNANDALE,NJ 08801

来源：

ENERGY & FUELS | 1990年 / 4卷 / 05期

关键词：

D O I：

10.1021/ef00023a025

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Thermolysis and neutral aquathermolysis of ring and N-substituted anilines showed either no reaction or little conversion. In phosphoric acid (10%) the anilines underwent denitrogenation to give phenols. Friedel-Crafts type alkylations and dealkylations were observed for alkyl-substituted anilines, together with the formation of diarylamines and carbazoles, both in runs with phosphoric acid and in runs with an aqueous sulfite/bisulfite mixture. Mechanistic pathways are suggested for the formation of all products. © 1990, American Chemical Society. All rights reserved.

引用

页码：547 / 555

页数：9

共 13 条

[1]

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[2]

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[4] AQUEOUS HIGH-TEMPERATURE CHEMISTRY OF CARBOCYCLES AND HETEROCYCLES .9. AQUATHERMOLYSIS OF ORTHO-SUBSTITUTED, META-SUBSTITUTED, AND MULTISUBSTITUTED PHENOLS IN THE PRESENCE AND ABSENCE OF SODIUM BISULFITE [J].