HEXASODIUM TRIHYDROGEN DECATUNGSTOSAMARATE OCTACOSAHYDRATE

被引:28
作者
OZEKI, T
YAMASE, T
机构
关键词
D O I
10.1107/S0108270193009965
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, Na6H3[SMW10O36].28H2O, consists of a decatungstosamarate anion, six fivefold- or sixfold-coordinated Na+ cations and water molecules of crystallization. The decatungstosamarate anion is comprised Of two [W5O18]6- moieties chelating to a central Sm3+ cation, which has tetragonal antiprismatic coordination with D4 symmetry and Sm-O distances of 2.41-2.46 angstrom.
引用
收藏
页码:327 / 330
页数:4
相关论文
共 15 条